Chloride stress corrosion cracking in austenitic stainless steel. This phenomenon is generally termed sulfide stress cracking ssc when operating at room temperature and stress corrosion cracking scc when operating at. The basic idea is to test under submerged conditions simulating the electrolyte composition and concentration of sea water during evaporation. Chloride stress corrosion cracking is a well known form of scc, typically caused by inadvertently contaminating equipment with chlorides.
There are several types of stress corrosion cracking scc, for example, chlorideinduced scc and h 2 sinduced scc. Chloride stress corrosion cracking clscc is one the most common reasons why austenitic stainless steel pipework and vessels deteriorate in the chemical processing and petrochemical industries. Astm g36 evaluating scc resistance of metals and alloys in boiling magnesium chloride. Stress corrosion cracking scc is the cracking induced from the combined influence of tensile stress and a corrosive environment. Assessment of susceptibility to chloride stress corrosion. It occurs in austenitic stainless steel under tensile stress in the presence of oxygen, chloride ions and high temperature. When stainless steels are fully immersed, it is rare to see chloride stress corrosion cracking at temperatures below 60 c 150 f. A critical study of stress corrosion cracking testing.
When stress corrosion cracking scc is suspected, our metallurgical analysis team can quickly provide you with testing, inspection, and analysis services to help determine the size and scope of the problems. Tests for stress corrosion stress corrosion cracking is a timedependent process in which a metallurgically susceptible material fractures prematurely due to the synergistic interaction of a corrosive environment and sustained tensile stress at the metal surface. Austenitic stainless steel may be susceptible to chloride stress corrosion cracking cscc. Chloride stress corrosion cracking clscc is a type of stress corrosion cracking scc and is one of the most well known forms of scc in the refining and chemical processing industries.
Mechanism of chloride stress corrosion cracking of. The laboratory testing fails to provide the exact field environmental conditions. Sulfide stress cracking nace mr01752002, mr0175iso 15156. It can be detrimental to austenitic stainless steels, one of the main reasons these steels are not considered a cureall for corrosion problems. This makes these plants susceptible to chlorideinduced stress corrosion cracking cscc. In this talk we described some of the test methods that may be used for each metal. G15 terminology relating to corrosion and corrosion testing. Scc stress corrosion cracking nace tm0177 sider test srl.
The impact of scc on a material usually falls between dry cracking and the fatigue threshold of that material. Electrochemical studies were made in aqueous licl, mgcl 2, and mgbr 2 solutions and in zncl 2 kcl molten salt to clarify the corrosion reactions related to stress corrosion cracking scc of austenitic stainless steel and to better define environmental variables critical to the occurrence of chloride scc. This test method is performed in 25% by mass sodium chloride acidified to ph 1. Dunn nrcnmsssfst public meetingggy with nuclear energy institute on chloride induced stress corrosion cracking regulatory issue resolution protocol august 5, 2014.
Chlorideinduced stress corrosion cracking tests and example. Chloride stress corrosion cracking inspectioneering. We also showed that different test methods can give different results for the same metal alloy. Chloride stress corrosion cracking scc of type 304 and 304l austenitic stainless steels ss was studied by a constant load method in air at a temperature of 353 k with relative humidity rh of. The test addresses the resistance of metals to cracking failure under the combined action of tensile stress and corrosion in aqueous environments conatining hydrogen sulfide h 2 s. The boiling magnesium chloride test cracks materials with the nickel levels found in relatively resistant austenitic and duplex stainless steels, thus making comparisons and evaluations for many service environments difficult.
Testing and evaluation methods for stress corrosion. Testing and evaluation methods for stress corrosion cracking. Chloride stress corrosion involves selective attack of a metal along its grain boundaries. It is a method for detecting the effects of composition, heat treatment, surface finish, microstructure, and stress on the susceptibility of these materials to chloride stress corrosion cracking. Deterioration by clscc can lead to failures that have the potential to release stored energy andor hazardous substances. Stresses can occur for a variety of reasons, including welding, physical damage, forming, machining, grinding, heat treatment, and operating stresses. Review and assessment of techniques for monitoring. Chloride stress corrosion cracking cscc is a type of intergranular corrosion. A cost efficient field test setup for cscc was designed and developed for. In nace mr0175iso 15156, however, but both ssc and chloride stress corrosion cracking scc are considered. G16 guide for applying statistics to analysis of corrosion data. A new method for assessment of susceptibility to chloride stress corrosion cracking under severe evaporative conditions has been developed. Chloride induced stress corrosion cracking of type 304 and. In general, this test method is more useful for stainless steels than the boiling magnesium chloride test of practice g36.
Further progress is then a process alternating between corrosion and mechanical cracking until the material fails completely. Stress corrosion cracking scc may be defined as the delayed failure of alloys by cracking when exposed to certain environments in the presence of a static tensile stress. The standard 304304l and 316316l grades are most susceptible. Developing field test procedures for chloride stress corrosion. Standard test methods for chemical analysis of thermal. The development of standardised methods of testing is a key element in the prevention of stress corrosion cracking scc in order to provide a unified reference framework. This chapter begins with a stress corrosion cracking scc definition and characteristics, testing methods common to scc and hydrogeninduced cracking, fracture mechanics principles and techniques, and corrosion fatigue testing. G36 practice for evaluating stress corrosion cracking resistance of metals and alloys in a boiling magnesium chloride solution. The relationship between corrosion fatigue and stress. Chloride induced stress corrosion cracking tests and example aging management program darrell s. For a given alloy, the testing result depends on the stress state and environment.
It can lead to unexpected sudden failure of normally ductile metal alloys subjected to a tensile stress, especially at elevated temperature. Stress corrosion cracking scc is the growth of crack formation in a corrosive environment. The laboratory testing fails to provide the exact field. There are, consequently, a number of approaches that we can use to prevent scc, or at least to give an acceptable lifetime. This type of failure is known as stress corrosion cracking, often abbreviated to scc. The environmental factors that increase the cracking susceptibility include higher temperatures, increased chloride content, lower ph, and higher levels of tensile stress. The slowstrainrate testing method was used for type 304l stainless. Stress corrosion cracking scc 1 is a common and dangerous form of cracking that occurs due to the combination of stress and corrosive environments 2. Corrosion under insulation cui is a severe problem for 304 stainless steel pressure vessel. Sulfide stress corrosion cracking of steels corrosion.
Some of these methods may be useful for monitoring the condition of used mwf, but. The chloride stresscorrosion cracking behavior of stainless steels. While no stainless steel can be completely immune, swageloks alloy 316 stainless steel fittings have performed exceptionally well in testing. This part of the work included metallurgical testing and an engineering critical assessment of the reactors structural integrity. The required tensile stresses may be in the form of directly applied stresses or in the form of residual. Standard practice for evaluating stresscorrosioncracking.
The tensile stress may be residual stress resulting from heat treatment. Stress corrosion cracking scc inspection and consulting services. Methods of minimizing chloride stress corrosion cracking. This forms of corrosion is typical of certain combination of metalenvironments. Developing field test procedures for chloride stress. Chloride induced stress corrosion cracking scc is one of the failure modes of stainless steels. The scc stress corrosion cracking test is meant to evaluate the susceptibility of metallic materials to cracking failure under the combined action of tensile strenght and corrosion in solutions containing hydrogen sulfide h 2 s at high temperatures. Controlling stress corrosion cracking scc in order for scc to occur, we require a susceptible material, an environment that will cause cracking of that material and a high enough stress or stress intensity factor. The selection of a stress corrosion cracking scc test which procures a reliable classification of stainless steels with regard to their scc resistance in chloride media requires the choice of a suitable electrolyte in which the passive film is similar to those built in industrial conditions and the choice of a reliable mechanical testing mode. A range of test methods is available in the form of international and national standards and procedures, comprising a wide variety of test methods for assessing scc and also. G30 practice for making and using ubend stress corrosion test specimens. Highly alloyed austenitic stainless steels s32654, s31254, and n08028, and duplex grades s32750 and s31803 possess much improved resistance to scc compared with s30400 and s31600 steels. Although this test may be performed using various concentrations of magnesium chloride, this procedure covers a test solution held at a constant boiling temperature of 155.
Stress corrosion cracking an overview sciencedirect topics. With the development of a database, ssdata, experimental data collected from calcium chloride tests, autoclave. Oct 21, 2019 chloride stress corrosion cracking cscc is a type of intergranular corrosion. Stress corrosion cracking scc is characterized by cracks propagating either transgranularly or intergranularly along grain boundaries. It has been shown that, for some materials, fine pitting is needed to start the activity. This makes these plants susceptible to chloride induced stress corrosion cracking cscc. Test methods for scc often give relatively good correspondence with real applications, but ranking is often doubtful, and comparisons of different material types. Assessment of susceptibility to chloride stress corrosion cracking of. Astm g123 002015 standard test method for evaluating. A corrosive medium especially chloridebearing or hydrogensulphide h 2 s media. Critical nominal stress and critical stress intensity factors for sulfide stress corrosion cracking of various steels were determined using fatigueprecracked, laboratory, cantilever beam specimens and short lengths of oil field casing and tubing pressured to failure. Standard test method for evaluating stresscorrosion cracking of stainless alloys with different nickel content in boiling acidified sodium chloride solution. Polythionic acid stress corrosion cracking pascc is a type of intergranular stress corrosion that affects sensitized stainless steels in refineries processing feedstocks containing sulphur. The combined action of tensile stress with corrosive environment can lead to chloride stress corrosion cracking cscc.
Webcorr provides corrosion consultancy services, corrosion expert witness and corrosion short courses for inhouse training, online and distance learning. Increasing nickel content above 18 to 20% or the use of duplex, or ferritic stainless steels improves resistance to cscc. Mechanism of chloride stress corrosion cracking of austenitic. Astmg123 standard test method for evaluating stress. While clearly intended to be used only for oil field equipment, industry has applied mr0175 in to many other areas including refineries, lng plants, pipelines and natural gas.
The chloride stresscorrosion cracking behavior of stainless. Chapter 9 stress corrosion cracking chapter contents 9. Stress corrosion cracking scc of chloride exposed stainless steels under evaporative conditions has. The mechanism of stress corrosion cracking scc involves a very complicated sequence of corrosion and fracture. Oil and gas production and petrochemical plants in the arabian gulf are exposed to severe environmental conditions of high temperature and humidity. This damage mechanism primarily affects standard and high carbon stainless steels, but low carbon and chemically stabilized stainless steels may also be. Whenever stainless steel is exposed to chloride concentrations and stress levels, chloride stress corrosion cracking cscc can occur. This study is to identify factors responsible for loss of production due to problems in plant and equipment. Each has a unique corrosion concern associated with it. The importance of a conjoint action of corrosion and stress as well as the nature of. Stress corrosion cracking the international institute of. Possibly monitoring stress corrosion cracking of dcss 4 when exposed to certain brines, austenitic stainless steel has exhibited susceptibility to stress corrosion cracking scc, which could compromise the integrity of the canister nrc identified scc as one of the three top priority degradation mechanisms that need to be addressed. Astm g123 002015 standard test method for evaluating stress.
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